danДоклады Национальной академии наук БеларусиDoklady of the National Academy of Sciences of Belarus1561-83232524-2431The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8323-2021-65-5-576-581dan-1007Research ArticleХИМИЯCHEMISTRYПолучение алюмосиликатных нанотрубок из природного каолинаObtaining alumi- nosilicate nanotubes from natural kaolinАгабековВ. Е.AgabekovV. E.

Агабеков Владимир Енокович – академик, д-р хим. наук, профессор, заведующий отделом

ул. Скорины, 36, 220141, Минск

 

Agabekov Vladimir E. – Academician, D. Sc. (Che mistry), Professor, Head of the Department

36, Skorina Str., 220141, Minsk

mixa@ichnm.byСидоренкоА. Ю.SidorenkoA. Yu.

Сидоренко Александр Юрьевич – канд. хим. наук, заведующий лабораторией

ул. Скорины, 36, 220141, Минск

Sidorenko Alexander Yu. – Ph. D. (Chemistry), Head of the Laboratory

36, Skorina Str., 220141, Minsk

sidorenko@ichnm.byСвиридоваТ. В.SviridovaT. V.

Свиридова Татьяна Викторовна – д-р хим. наук, доцент

пр. Независимости, 4, 220030, Минск

Sviridova Tatiana V. – D. Sc. (Chemistry), Associate professor

4, Nezavisimosti Ave., 220030, Minsk

tsviridova75@gmail.comКурбанЮ. М.KurbanYu. M.

Курбан Юлия Михайловна – мл. науч. сотрудник

ул. Скорины, 36, 220141, Минск

Kurban Yulia M. – Junior researcher

36, Skorina Str., 220141, Minsk

kurban@ichnm.byСвиридовД. В.SviridovD. V.

Свиридов Дмитрий Вадимович – член-корреспондент, д-р хим. наук, профессор, декан

пр. Независимости, 4, 220030, Минск

Sviridov Dmitry V. – Corresponding Member, D. Sc. (Chemistry), Professor, Dean

4, Nezavisimosti Ave., 220030, Minsk

Sviridov@bsu.byИнститут химии новых материалов Национальной академии наук БеларусиInstitute of Chemistry of New Materials of the National Academy of Sciences of BelarusБелорусский государственный университетBelarusian State University202107112021655576–581Copyright © Агабеков В.Е., Сидоренко А.Ю., Свиридова Т.В., Курбан Ю.М., Свиридов Д.В., 20212021Агабеков В.Е., Сидоренко А.Ю., Свиридова Т.В., Курбан Ю.М., Свиридов Д.В.Agabekov V.E., Sidorenko A.Y., Sviridova T.V., Kurban Y.M., Sviridov D.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://doklady.belnauka.by/jour/article/view/1007

На основе природного каолина месторождения «Дедовка» (Гомельская обл.) впервые получены алюмосиликатные нанотрубки длиной 800–1100 нм и диаметром 50–60 нм. Синтез осуществлен по разработанной методике в относительно мягких условиях при температуре 60–66 °С, атмосферном давлении и низком (7,0 мл/г) количестве реагента (метанол), необходимого для их формирования.

The analysis of the trajectories of molecular dynamics On the basis of natural kaolin from the “Dedovka” deposit (Gomel region), aluminosilicate nanotubes 800– 1100 nm in length and 50–60 nm in diameter were obtained for the first time. The synthesis was carried out according to the developed method under relatively mild conditions at a temperature of 60–66 °C, atmospheric pressure, and a low (7.0 mL/g) amount of a reagent (methanol) required for their formation.

каолиналюмосиликатные нанотрубкиинтеркаляцияметанолkaolinaluminosilicate nanotubesintercalationmethanolReferencesMassaro, M. Past, present and future perspectives on halloysite clay minerals / M. Massaro, R. Noto, S. Riela // Molecules. – 2020. – Vol. 25, N 20. – Art. 4863. https://doi.org/10.3390/molecules25204863Massaro, M. Past, present and future perspectives on halloysite clay minerals / M. Massaro, R. Noto, S. Riela // Molecules. – 2020. – Vol. 25, N 20. – Art. 4863. https://doi.org/10.3390/molecules25204863Mahajan, A. Halloysite nanotubes based heterogeneous solid acid catalysts / A. Mahajan, P. Gupta // New Journal of Chemistry. – 2020. – Vol. 44, N 30. – P. 12897–12908. https://doi.org/10.1039/d0nj02846kMahajan, A. Halloysite nanotubes based heterogeneous solid acid catalysts / A. Mahajan, P. Gupta // New Journal of Chemistry. – 2020. – Vol. 44, N 30. – P. 12897–12908. https://doi.org/10.1039/d0nj02846kHighly selective Prins reaction over acid-modified halloysite nanotubes for synthesis of isopulegol-derived 2H-chromene compounds / A. Yu. Sidorenko [et al.] // Journal of Catalysis. – 2019. – Vol. 374. – P. 360–377. https://doi.org/10.1016/j.jcat.2019.05.009Highly selective Prins reaction over acid-modified halloysite nanotubes for synthesis of isopulegol-derived 2H-chromene compounds / A. Yu. Sidorenko [et al.] // Journal of Catalysis. – 2019. – Vol. 374. – P. 360–377. https://doi.org/10.1016/j.jcat.2019.05.009From platy kaolinite to aluminosilicate nanoroll via one-step delamination of kaolinite: effect of the temperature of intercalation / P. Yuan [et al.] // Applied Clay Science. – 2013. – Vol. 83–84. – P. 68–76. https://doi.org/10.1016/j.clay.2013.08.027From platy kaolinite to aluminosilicate nanoroll via one-step delamination of kaolinite: effect of the temperature of intercalation / P. Yuan [et al.] // Applied Clay Science. – 2013. – Vol. 83–84. – P. 68–76. https://doi.org/10.1016/j.clay.2013.08.027A comparative study of synthetic tubular kaolinite nanoscrolls and natural halloysite nanotubes / X. Li [et al.] // Applied Clay Science. – 2019. – Vol. 168. – P. 421–427. https://doi.org/10.1016/j.clay.2018.12.014A comparative study of synthetic tubular kaolinite nanoscrolls and natural halloysite nanotubes / X. Li [et al.] // Applied Clay Science. – 2019. – Vol. 168. – P. 421–427. https://doi.org/10.1016/j.clay.2018.12.014Liu, Q. Insight into the self-adaptive deformation of kaolinite layers into nanoscrolls / Q. Liu, X. Li, H. Cheng // Applied Clay Science. – 2016. – Vol. 124–125. – P. 175–182. https://doi.org/10.1016/j.clay.2016.02.015Liu, Q. Insight into the self-adaptive deformation of kaolinite layers into nanoscrolls / Q. Liu, X. Li, H. Cheng // Applied Clay Science. – 2016. – Vol. 124–125. – P. 175–182. https://doi.org/10.1016/j.clay.2016.02.015An efficient method to prepare aluminosilicate nanoscrolls under mild conditions / S. Zhang [et al.] // ChemComm. – 2021. – Vol. 57, N 6. – P. 789–792. https://doi.org/10.1039/d0cc07291eAn efficient method to prepare aluminosilicate nanoscrolls under mild conditions / S. Zhang [et al.] // ChemComm. – 2021. – Vol. 57, N 6. – P. 789–792. https://doi.org/10.1039/d0cc07291eQu, H. Efficient preparation of kaolinite/methanol intercalation composite by using a Soxhlet extractor / H. Qu, S. He, H. Su // Scientific reports. – 2019. – Vol. 9, N 1. – P. 1–8. https://doi.org/10.1038/s41598-019-44806-yQu, H. Efficient preparation of kaolinite/methanol intercalation composite by using a Soxhlet extractor / H. Qu, S. He, H. Su // Scientific reports. – 2019. – Vol. 9, N 1. – P. 1–8. https://doi.org/10.1038/s41598-019-44806-yКомаров, В. С. Адсорбционно-структурные, физико-химические и каталитические свойства глин Белоруссии / В. С. Комаров. – Минск, 1970. – 318 c.Komarov V. S. Adsorption-structural, physicochemical and catalytic properties of clays of Belarus. Minsk, 1970. 318 p. (in Russian).Комаров, В. С. Синтез и регулирование пористой структуры адсорбентов / В. С. Комаров. – Минск, 2003. – 276 с.Komarov V. S. Synthesis and regulation of the porous structure of adsorbents. Minsk, 2003. 276 p. (in Russian).Комаров, В. С. Адсорбенты: получение, структура, свойства / В. С. Комаров, А. И. Ратько. – Минск, 2009. – 256 с.Komarov V. S., Ratko A. I. Adsorbents: obtaining, structure, properties. Minsk, 2009. 256 p. (in Russian).Дятлова, Е. М. Структурные особенности природных и обогащенных каолинов месторождений Республики Беларусь / Е. М. Дятлова, О. А. Сергиевич, Н. М. Бобкова // Вес. Нац. акад. навук Беларусі. Сер. хім. навук. – 2018. – Т. 54, № 1. – С. 96–102. https://doi.org/10.29235/1561-8331-2018-54-1-96-102Dyatlova E. M., Sergievich O. A., Bobkova N. M. Investigation of structural features of natural and enriched kaolins of the Republic of Belarus by IR-spectroscopy. Vestsi Natsyianal’nai akademii navuk Belarusi. Seryya khimichnykh navuk=Proceedings of the National Academy of Sciences of Belarus, Сhemical series, 2018, vol. 54, no. 1, pp. 96–102 (in Russian). https://doi.org/10.29235/1561-8331-2018-54-1-96-102

The authors declare that there are no conflicts of interest present.