danДоклады Национальной академии наук БеларусиDoklady of the National Academy of Sciences of Belarus1561-83232524-2431The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8323-2022-66-2-148-155dan-1049Research ArticleФИЗИКАPHYSICSУправление фотостабильностью полупроводниковых квантовых точек с помощью наночастиц золотаManipulation of the quantum dots photostability using gold nanoparticleshttps://orcid.org/0000-0001-8618-6771КулаковичО. С.KulakovichO. S.

Кулакович Ольга Сергеевна – кандидат химических наук, ведущий научный сотрудник

пр. Независимости, 68-2, 220072

Kulakovich Olga S. – Ph. D. (Chemistry), Leading Researcher

68-2, Nezavisimosti Ave., 220072, Minsk

o.kulakovich@ifanbel.basnet.byГуриновичЛ. И.GurinovichL. I.

Гуринович Леонид Иванович – кандидат физико-математических наук, старший научный сотрудник

пр. Независимости, 68-2, 220072

Gurinovich Leonid I. – Ph. D. (Physics and Mathematics), Senior Researcher

68-2, Nezavisimosti Ave., 220072, Minsk

leonid@dragon.bas-net.byhttps://orcid.org/0000-0003-2072-3970ТроцюкЛ. Л.TrotsiukL. I.

Троцюк Людмила Леонидовна – кандидат химических наук, старший научный сотрудник

пр. Независимости, 68-2, 220072

Trotsiuk Liudmila L. – Ph. D. (Chemistry), Senior Researcher

68-2, Nezavisimosti Ave., 220072, Minsk

l.trotsiuk@ifanbel.bas-net.byhttps://orcid.org/0000-0002-6336-0578РоманенкоА. А.RamanenkaA. A.

Романенко Андрей Алексеевич – научный сотрудник

пр. Независимости, 68-2, 220072

Ramanenka Andrey A. – Researcher

68-2, Nezavisimosti Ave., 220072, Minsk

a.ramanenka@ifanbel.bas-net.byhttps://orcid.org/0000-0002-3378-0870ЛиХонгбоLiHongbo

Хонгбо Ли – профессор

5, South Zhongguancun Street, Beijing 10008

Hongbo Li – Professor

5, South Zhongguancun Street, Beijing 10008

hongbo.li@bit.edu.cnМатвеевскаяН. А.MatveevskayaN. A.

Матвеевская Неонилла Анатольевна – кандида технических наук, старший научный сотрудник

пр. Ленина, 60, 61001, Харьков

Matveevskaya Neonolla A. – Ph. D. (Engineering), Senior Researcher

60, Lenin Ave., 61001, Kharkiv

neonillamatveevskaa@gmail.comГапоненкоС. В.GaponenkoS. V.

Гапоненко Сергей Васильевич – академик, доктор физико-математических. наук, профессор

пр. Независимости, 68-2, 220072

Gaponenko Sergey V. – Academician, D. Sc. (Physics and Mathematics), Professor

68-2, Nezavisimosti Ave., 220072, Minsk

s.gaponenko@ifanbel.bas-net.byИнститут физики имени Б. И. Степанова Национальной академии наук БеларусиB. I. Stepanov Institute of Physics of the National Academy of Sciences of BelarusПекинский технологический институтBeijing Institute of TechnologyИнститут монокристаллов Национальной академии наук УкраиныInstitute for Single Crystals of the National Academy of Sciences of Ukraine202206052022662148155Copyright © Кулакович О.С., Гуринович Л.И., Троцюк Л.Л., Романенко А.А., Ли Х., Матвеевская Н.А., Гапоненко С.В., 20222022Кулакович О.С., Гуринович Л.И., Троцюк Л.Л., Романенко А.А., Ли Х., Матвеевская Н.А., Гапоненко С.В.Kulakovich O.S., Gurinovich L.I., Trotsiuk L.I., Ramanenka A.A., Li H., Matveevskaya N.A., Gaponenko S.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://doklady.belnauka.by/jour/article/view/1049

Установлено влияние наночастиц золота различной формы (наносферы и наностержни) на фотостабильность квантовых точек InP/ZnSe/ZnSeS/ZnS и CdSe/ZnCdS/ZnS со структурой типа «ядро/оболочка». Наносферы золота повышают фотостабильность квантовых точек InP/ZnSe/ZnSeS/ZnS при возбуждении излучением синего диапазона за счет уменьшения среднего времени жизни возбужденного состояния квантовых точек и, соответственно, снижения вероятности Оже-процессов. Увеличение среднего времени жизни возбужденного состояния квантовых точек CdSe/ZnCdS/ZnS в комплексах с наностержнями золота приводит к снижению фотостабильности при возбуждении на 449 и 532 нм.

The effect of plasmonic films containing gold nanoparticles of different shape (nanospheres and nanorods) on the photostability of InP/ZnSe/ZnSeS/ZnS and CdSe/ZnCdS/ZnS quantum dots with core/shell structure has been determined. Gold nanospheres increase the photostability of InP/ZnSe/ZnSeS/ZnS quantum dots when excited by blue LED radiation when reducing the average lifetime of the excited state of quantum dots and, accordingly, when reducing the probability of Auger processes. An increase in the average lifetime of the excited state of CdSe/ZnCdS/ZnS quantum dots in complexes with gold nanorods leads to a decrease in the photostability upon excitation at 449 and 532 nm.

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The authors declare that there are no conflicts of interest present.