danДоклады Национальной академии наук БеларусиDoklady of the National Academy of Sciences of Belarus1561-83232524-2431The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8323-2018-62-2-185-192dan-507Research ArticleХИМИЯCHEMISTRYПОЛУЧЕНИЕ И СВОЙСТВА ТОНКОПЛЕНОЧНЫХ КОМПОЗИЦИОННЫХ ПОЛОВОЛОКОННЫХ МЕМБРАН ДЛЯ УЛЬТРАФИЛЬТРАЦИИ С НИЗКИМ НОМИНАЛЬНЫМ МОЛЕКУЛЯРНО-МАССОВЫМ ПРЕДЕЛОМ ОТСЕЧЕНИЯFULLERENOL-POLYAMIDE THIN FILM COMPOSITE HOLLOW FIBER MEMBRANES FOR LOW MOLECULAR WEIGHT CUT-OFF ULTRAFILTRATIONБильдюкевичА. В.BildyukevichA. V.

академик, д-р хим. наук, профессор, директор

Academician, D. Sc. (Chemistry), Professor, Director

uf@ifoch.bas-net.byПлискоТ. В.PliskoT. V.

канд. хим. наук, ст. науч. сотрудник

Ph. D (Chemistry), Senior researcher

plisko.v.tatiana@gmail.comЛюбимоваЕ. С.LiubimovaA. S.

науч. сотрудник

Researcher

liubimova_elena@mail.ruПеньковаА. В.PenkovaA. V.

канд. хим. наук, доцент

Ph. D. (Chemistry), Associate Professor

a.penkova@spbu.ruДмитренкоМ. Е.DmitrenkoM. E.

ассистент

Assistant

dmitrenko.me@mail.ruИнститут физико-органической химии Национальной академии наук Беларуси, МинскInstitute of Physical Organic Chemistry of the National Academy of Sciences of Belarus, MinskСанкт-Петербургский государственный университет, Санкт-ПетербургSaint-Petersburg State University, Saint Petersburg201820052018622185192Copyright © Бильдюкевич А.В., Плиско Т.В., Любимова Е.С., Пенькова А.В., Дмитренко М.Е., 20182018Бильдюкевич А.В., Плиско Т.В., Любимова Е.С., Пенькова А.В., Дмитренко М.Е.Bildyukevich A.V., Plisko T.V., Liubimova A.S., Penkova A.V., Dmitrenko M.E.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://doklady.belnauka.by/jour/article/view/507

Тонкопленочные композиционные мембраны (ТКМ) для ультрафильтрации с низким номинальным молекулярно-массовым пределом отсечения были получены при введении добавок фуллеренола C60(OH)24 в селективный полиамидный (ПА) слой, сформированный методом межфазной поликонденсации при использовании в качестве подложки половолоконной ультрафильтрационной мембраны на основе полисульфона. Межфазную поликонденсацию с образованием тонкого полиамидного слоя проводили при последовательной фильтрации раствора триэтилентетрамина (ТЭТА) в воде и раствора изофталоилхлорида в гексане через половолоконную мембрану. При увеличении концентрации фуллеренола в водном растворе ТЭТА угол смачивания селективного слоя уменьшается с 34 до 21°. Показано, что устойчивость к засорению ТКМ ПА/фуллеренол выше, чем исходной немодифицирован- ной мембраны. Мембраны, полученные с использованием 0,3–0,75 % дисперсий фуллеренола в растворе ТЭТА, характеризовались максимальным значением восстановления потока после фильтрации раствора лизоцима.

 

Fullerenol C60(OH)24 was incorporated into a polyamide (PA) selective layer to develop novel thin film nanocomposite (TFN) hollow fiber membranes for low molecular weight cut-off ultrafiltration. TFN membranes were fabricated using the interfacial polycondensation technique by alternately pumping a fullerenol dispersion into the triethylenetetramine (TETA) aqueous solution and the isophthaloyl chloride solution into hexane through polysulfone hollow fiber membranes. The contact angle of the skin layer was found to decrease sharply from 34 to 21° when the concentration of fullerenol increases up to 0.5 wt. % in the TETA aqueous solution. Antifouling properties of the PA/fullerenol membranes were found to be superior to the initial membrane. The maximum fouling recovery ratio was observed for the TFN membrane with 0.3–0.75 wt. % of fullerenol in the TETA aqueous solution.

 

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The authors declare that there are no conflicts of interest present.