danДоклады Национальной академии наук БеларусиDoklady of the National Academy of Sciences of Belarus1561-83232524-2431The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8323-2020-64-4-426-430dan-899Research ArticleХИМИЯCHEMISTRYПолучение хиральных изобензофуранов на основе 3-карена в присутствии галлуазитовых нанокатализаторовPreparation of chiral izobenzofuranes based on 3-carene in the presence of halloysite nanocatalystsСидоренкоА. Ю.SidorenkoA. Yu.

Сидоренко Александр Юрьевич - кандидат химических наук, заведующий лабораторией, ИХНМ НАН Беларуси.

ул. Скорины, 36, 220141, Минск.

Sidorenko Alexander Yu. - Ph. D. (Chemistry), Head of the Laboratory, Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus.

36, Skorina Str., 220141, Minsk.

sidorenko@ichnm.basnet.byАгабековВ. Е.AgabekovV. E.

Агабеков Владимир Енокович - академик, доктор химических наук, профессор, директор, ИХНМ НАН Беларуси.

ул. Скорины, 36, 220141, Минск.

Agabekov Vladimir E. - Academician, D. Sc. (Chemistry), Professor, Director, Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus.

36, Skorina Str., 220141, Minsk.

mixa@ichnm.basnet.byВолчоК. П.VolchoK. P.

Волчо Константин Петрович - доктор химических наук, профессор, главный научный сотрудник, НИОХ СО РАН им. Н.Н. Ворожцова.

пр. Академика Лаврентьева, 9, 630090, Новосибирск.

Volcho Konstantin P. - D. Sc. (Chemistry), Professor, Chief researcher, Novosibirsk Institute of Organic Chemistry Siberian Branch of the Russian Academy of Sciences.

9, Lavrentiev Ave., 630090, Novosibirsk.

volcho@nioch.nsc.ruСалахутдиновН. Ф.SalakhutdinovN. F.

Салахутдинов Нариман Фаридович - член-корреспондент, доктор химических наук, профессор, руководитель отдела, НИОХ СО РАН им. Н.Н. Ворожцова.

пр. Академика Лаврентьева, 9, 630090, Новосибирск.

Salakhutdinov Nariman F. - Corresponding Member, D. Sc. (Chemistry), Professor, Head of the Department, Novosibirsk Institute of Organic Chemistry Siberian Branch of the Russian Academy of Sciences.

9, Lavrentiev Ave., 630090, Novosibirsk.

anvar@nioch.nsc.ruМурзинД. Ю.MurzinD. Yu.

Мурзин Дмитрий Юрьевич - доктор химических наук, профессор, заведующий лабораторией, Университет Або Академи.

Biskopsgatan 8, Turku-Abo, 20500.

Murzin Dmitry Yu. - D. Sc. (Chemistry), Professor, Head of the Laboratory, Abo Akademi University.

Biskopsgatan 8, Turku-Abo, 20500.

dmurzin@abo.fiИнститут химии новых материалов Национальной академии наук БеларусиInstitute of Chemistry of New Materials of the National Academy of Sciences of BelarusНовосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наукNovosibirsk Institute of Organic Chemistry of Siberian Branch of the Russian Academy of SciencesУниверситет Або АкадемиAbo Akademi University202030082020644426430Copyright © Сидоренко А.Ю., Агабеков В.Е., Волчо К.П., Салахутдинов Н.Ф., Мурзин Д.Ю., 20202020Сидоренко А.Ю., Агабеков В.Е., Волчо К.П., Салахутдинов Н.Ф., Мурзин Д.Ю.Sidorenko A.Y., Agabekov V.E., Volcho K.P., Salakhutdinov N.F., Murzin D.Y.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://doklady.belnauka.by/jour/article/view/899

Исследовано взаимодействие содержащих 2-карен продуктов изомеризации 3-карена с 4-метокси-бензальдегидом в присутствии обработанных 5,0 % HCl галлуазитовых нанотрубок. Основными продуктами реакции являются хиральные производные изобензофурана. Селективность по этим соединениям (71,4 %) сопоставима с таковой при использовании труднодоступного индивидуального 2-карена. Показана возможность использования галлуазитовых нанокатализаторов для селективного получения изобензофурановых соединений на основе продуктов изомеризации 3-карена (компонента живичного скипидара) без предварительного разделения смеси.

The reaction of a 2-carene containing mixture, obtained by 3-carene isomerization, with 4-methoxybenzalde-hyde in the presence of halloysite nanotubes treated with 5.0 % HCl was studied. The main reaction products are the chiral derivatives of isobenzofuran. Selectivity to these compounds (71.4 %) is comparable to that when only 2-carene is used as a reactant. Thus, the possibility is shown how to use halloysite nanocatalysts for selective production of isobenzofuran compounds based on 3-carene isomerization products (major component of turpentine) without preliminary mixture separation.

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The authors declare that there are no conflicts of interest present.