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Synthesis, structure and morphology of composites based on magnesium ferrite and carbon nitride

https://doi.org/10.29235/1561-8323-2021-65-2-178-184

Abstract

The composites based on magnesium ferrite and carbon nitride were synthesized by the sol-gel method in combination with thermochemical condensation. The effect of the synthesis method on the crystalline structure, the phase and chemical composition, and the morphology of composites was studied by the X-ray diffraction, IR spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy techniques. It was found that, depending on the conditions of the sol-gel stages, the initiation of self-combustion high-temperature synthesis and melanin thermochemical condensation, composites with different crystalline structure and morphology were prepared. The obtained results are important for the development of the heterogeneous Fenton- and photo-Fenton catalysts based on magnesium ferrite and carbon nitride composites.

About the Author

A. I. Ivanets
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Ivanets Andrei I., D. Sc. (Chemistry), Associate professor, Leading researcher

9/1, Surganov Str., 220072, Minsk



References

1. Zhao Z., Sun Y., Dong F. Graphitic carbon nitride based nanocomposites: a review. Nanoscale, 2015, vol. 7, no. 1, pp. 15–37. https://doi.org/10.1039/c4nr03008g

2. Liang Q., Shao B., Tong S., Liu Z., Tang L., Liu Y., Cheng M., He Q., Wu T., Pan Y., Huang J., Peng Z. Recent advances of melamine self-assembled graphitic carbon nitride-based materials: Design, synthesis and application in energy and environment. Chemical Engineering Journal, 2021, vol. 405, pp. 126951. https://doi.org/10.1016/j.cej.2020.126951

3. Shorie M., Kaur H., Chadha G., Singh K., Sabherwal P. Graphitic carbon nitride QDs impregnated biocompatible agarose cartridge for removal of heavy metals from contaminated water samples. Journal of Hazardous Materials, 2019, vol. 367, pp. 629–638. https://doi.org/10.1016/j.jhazmat.2018.12.115

4. Ivanets A., Prozorovich V. Effect of melamine acidic treatment on g-C3N4 physicochemical properties and catalytic activity. Water and Water Purification Technologies. Scientific and Technical News, 2020, vol. 28, pp. 26–36.

5. Maeda K., Wang X., Nishihara Y., Lu D., Antonietti M., Domen K. Photocatalytic activities of graphitic carbon nitride powder for water reduction and oxidation under visible light. Journal of Physical Chemistry C, 2009, vol. 113, no. 12, pp. 4940–4947. https://doi.org/10.1021/jp809119m

6. Ma S., Zhan S., Jia Y., Shi Q., Zhou Q. Enhanced disinfection application of Ag-modified g-C3N4 composite under visible light. Applied Catalysis B: Environmental, 2016, vol. 186, pp. 77−87. https://doi.org/10.1016/j.apcatb.2015.12.051

7. Gao G., Zhang L., Chen Q., Fan H., Zheng J., Fang Y., Duan R., Cao X., Hu X. Self-assembly approach toward polymeric carbon nitrides with regulated heptazine structure and surface groups for improving the photocatalytic performance. Chemical Engineering Journal, 2021, vol. 409, pp. 127370. https://doi.org/10.1016/j.cej.2020.127370

8. Hassani A., Eghbali P., Ekicibil A., Metin O. Monodisperse cobalt ferrite nanoparticles assembled on mesoporous graphitic carbon nitride (CoFe2O4/mpg-C3N4): a magnetically recoverable nanocomposite for the photocatalytic degradation of organic dyes. Journal of Magnetism and Magnetic Materials, 2018, vol. 456, pp. 400–412. https://doi.org/10.1016/j. jmmm.2018.02.067

9. Aksoy M., Yanalak G., Aslan E., Patir I. H., Metin O. Visible light-driven hydrogen evolution by using mesoporous carbon nitride-metal ferrite (MFe2O4/mpg-CN; M: Mn, Fe, Co and Ni) nanocomposites as catalysts. International Journal of Hydrogen Energy, 2020, vol. 45, no. 33, pp. 16509–16518. https://doi.org/10.1016/j.ijhydene.2020.04.111

10. Ivanets A., Prozorovich V., Roshchina M., Kouznetsova T., Budeiko N., kulbitskaya L., Hosseini-Bandegharaei A., Masindi V., Pankov V. A comparative study on the synthesis of magnesium ferrite for the adsorption of metal ions: Insights into the essential role of crystallite size and surface hydroxyl groups. Chemical Engineering Journal, 2021, vol. 411, pp. 128523. https://doi.org/10.1016/j.cej.2021.128523


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ISSN 1561-8323 (Print)
ISSN 2524-2431 (Online)