Preview

Doklady of the National Academy of Sciences of Belarus

Advanced search

Effect of a nonionic surfactant and anionic polyelectrolyte binary system on the stability of a calcium and magnesium carbonates dispersion

https://doi.org/10.29235/1561-8323-2023-67-6-473-480

Abstract

The effect of sodium polyacrylate, polyethylene glycol of various molecular weights, and their mixtures on the dispersion stability of calcium and magnesium carbonates was studied. It was shown that in the presence of a binary system, the light transmission of the dispersion decreases 1.2–1.5 times, the content of fine fraction particles increases by 1.1–1.3 times compared to the individual components. The stability of the dispersion of carbonates depends on the components ratio in the binary system and their molecular weight. The formation of adsorption solvated layers of polyacrylate and polyethylene glycol molecules at the interphase boundary contributes to an increase in the stability of the carbonate dispersion.

About the Authors

S. V. Bucha
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Russian Federation

Bucha Sviatlana V. – Researcher.

9/1, Surganov Str., 220072, Minsk



A. D. Vorobiev
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Russian Federation

Vorobiev Artem D. ‒ Ph. D. (Engineering), Leading Researcher.

9/1, Surganov Str., 220072, Minsk



D. V. Cherednichenko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Russian Federation

Сherednichenko Denis V. – Ph. D. (Chemistry), Leading Researcher.

9/1, Surganov Str., 220072, Minsk



E. V. Vorobieva
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Russian Federation

Vorobieva Elena V. – D. Sc. (Chemistry), Associate Professor, Head of the Laboratory.

9/1, Surganov Str., 220072, Minsk



E. V. Laevskaya
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Russian Federation

Layevskaya Еlena V. – Ph. D. (Engineering), Head of the Laboratory.

9/1, Surganov Str., 220072, Minsk



N. P. Krutko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Russian Federation

Krutko Nikolay P. – Academician, D. Sc. (Chemistry), Professor, General Director.

9/1, Surganov Str., 220072, Minsk



H. V. Bondareva
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Russian Federation

Bondareva Halina V. ‒ Ph. D. (Chemistry), Scientific Secretary.

9/1, Surganov Str., 220072, Minsk



References

1. Kovalev D. M., Kravchenko V. S., Potemkin I. I. Nanofoam-like structure of surfactants in oil-water mixtures. Journal of Molecular Liquids, 2022, vol. 360, pp. 119568–119591. https://doi.org/10.1016/j.molliq.2022.119568

2. Anisimova S. V. Stabilization of biocidal compositions based on aqueous dispersions of acrylic copolymers. Lakokrasochnaja promyshlennost’ = Paint & Coatings Industry, 2007, no. 2, pp. 2–4 (in Russian).

3. Reddy M. M., Hoch A. R. Calcite crystal growth rate inhibition by polycarboxylic acids. Journal of Colloid and Interface Science, 2001, vol. 235, no. 2, pp. 365–370. https://doi.org/10.1006/jcis.2000.7378

4. Shestak I. V., Vorobieva E. V., Basalyha I. I., Krutko N. P., Kulbitskaya L. V. Polyacrylic acid and polyethylene glycol influence on the crystallization of calcium carbonates and magnesium. Doklady Natsional’noi akademii nauk Belarusi = Doklady of the National Academy of Sciences of Belarus, 2010, vol. 54, no. 2, pp. 77–81 (in Russian).

5. Holmberg K., Jjonsson B., Kronberg B., Lindman B. Surfactants and polymers in aqueous solutions. Мoscow, 2007. 528 p. (in Russian).

6. Shchukin E. D., Percov A. V., Amelina E. A. Colloid chemistry. Мoscow, 2004. 445 p. (in Russian).

7. Nechaev A. I., Voronina N. S., Valtsifer V. A., Strelnikov V. N. Stability of the dispersed system in inverse emulsion рolymerization of ionic acrylate monomers. Colloid and Polymer Science, 2021, vol. 299, pp. 1127–1138. https://doi.org/10.1007/ s00396-021-04832-7

8. Kim J.-W., Lee D., Shum H. C., Weitz D. A. Colloid surfactants for emulsion stabilization. Advanced Materials, 2008, vol. 20, no. 17, pp. 3239–3243. https://doi.org/10.1002/adma.200800484

9. Soboleva O. A., Krivobokova M. V. Mixed micelles and adsorption layers of nonionic surfactant with monomeric and dimeric cationic surfactants. Vestnik Moskovskogo Universiteta. Serija 2. Himija = Bulletin of Moscow University. Chemistry series, 2004, vol. 45, no. 5, pp. 344–349 (in Russian).

10. Guyomard A., Muller G., Glinel K. Buildup of multilayers based on amphiphilic polyelectrolytes. Macromolecules, 2005, vol. 38, no. 13, pp. 5737–5742. https://doi.org/10.1021/ma050867n

11. Desbrieres J., Babak V. G. Interfacial properties of amphiphilic systems on the basis of natural polymers-chitin derivatives. Russian Journal of General Chemistry, 2008, vol. 78, no. 11, pp. 2230–2238. https://doi.org/10.1134/s1070363208110443

12. Masimov E. A., Pashayev B. G., Hasanov H. S. Viscometric study of diluted aqueous solutions of polyethylene glycols of different molecular weights. Russian Journal of Physical Chemistry A, 2019, vol. 93, no. 5, pp. 988–990. https://doi.org/10.1134/s0036024419050224

13. Vorobeva E. V., Krutko N. P., Basalyga I. I., Matrunchik Ju. V. Polymer complexes based on polyacrylic acid, polyethylene glycol and polyvinyl alcohol. Vestsi Natsyyanal’nai akademii navuk Belarusi. Seryya khimichnykh navuk = Proceedings of the National Academy of Sciences of Belarus. Chemical series, 2008, no. 1, pp. 21–25 (in Russian).


Review

Views: 170


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1561-8323 (Print)
ISSN 2524-2431 (Online)