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Obtaining potassium sulphate by conversion of potassium chloride with ammonium sulfate

https://doi.org/10.29235/1561-8323-2025-69-4-291-295

Abstract

The process of obtaining potassium sulfate with a basic substance content of at least 95 % is realized under normal conditions. In order to achieve a high content of potassium sulfate in the product, an excess of potassium chloride relative to ammonium sulfate at a weight ratio of at least 1.6 is required. During the dissolution of potassium chloride in a solution of ammonium sulfate, the main factor of obtaining concentrated potassium sulphate is to get the purest possible nuclei of potassium sulfate crystals. The excess of potassium chloride resulting from the synthesis process is utilized by the production of NPKS-fertilizers in liquid and granulated forms.

About the Authors

А. I. Vaitenka
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Vaitenka Anatoli I. – Senior Researcher

9/1, Surganov Str., 220072, Minsk



A. A. Rat’ko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Russian Federation

Rat’ko Alexander A. – Ph. D. (Chemistry), Deputy Director

9/1, Surganov Str., 220072, Minsk



N. P. Krut’ko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Krut’ko Nikolay P. – Academician, D. Sc. (Chemistry), Professor, Head of the Department

9/1, Surganov Str., 220072, Minsk



V. V. Shevchuk
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Shevchuk Vyacheslav V. – Corresponding Member, D. Sc. (Chemistry), Head of the Laboratory

9/1, Surganov Str., 220072, Minsk



References

1. Umarova M., Dekhkanov Z., Aripov K. Obtaining potassium sulphate by conversion of potassium chloride and ammonium sulphate. E3S Web of Conferences, 2023, vol. 460, art. 09035. https://doi.org/10.1051/e3sconf/202346009035

2. Mubarak Y. Integrated process for potassium sulphate and a mixture of ammonium sulphate/potassium sulphate salts production. International Journal of Engineering and Technology, 2018, vol. 7, no. 1, pp. 185–197. https://doi.org/10.14419/ijet. v7i1.9188

3. Goncharik I. I., Aleksandrovich H. M. Conversion of potassium chloride and ammonium sulfate in the presence of urea. Himiya i himicheskaya tehnologiya [Chemistry and Chemical Technology]. Minsk, 1989, iss. 3, pp. 28–32 (in Russian).

4. Kashkarov O. D., Atadjanov A. Solubility isotherms of the aqueous system (K+, NH4+) (Cl, SO4–2) Н2O at 25 °С. Izvestiya Akademii nauk Turkmenskoi SSR. Seriya fiziko-tekhnicheskikh, khimicheskikh i geologicheskikh nauk [News of the Academy of Sciences of the Turkmen SSR. Series of physical, technical, chemical and geological sciences], 1972, no. 2, pp. 113–118 (in Russian).

5. Viktorov M. M. Graphical calculations in the technology of inorganic substances. Leningrad, 1972. 462 p. (in Russian).


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ISSN 1561-8323 (Print)
ISSN 2524-2431 (Online)