Preparation of chiral izobenzofuranes based on 3-carene in the presence of halloysite nanocatalysts
https://doi.org/10.29235/1561-8323-2020-64-4-426-430
Abstract
The reaction of a 2-carene containing mixture, obtained by 3-carene isomerization, with 4-methoxybenzalde-hyde in the presence of halloysite nanotubes treated with 5.0 % HCl was studied. The main reaction products are the chiral derivatives of isobenzofuran. Selectivity to these compounds (71.4 %) is comparable to that when only 2-carene is used as a reactant. Thus, the possibility is shown how to use halloysite nanocatalysts for selective production of isobenzofuran compounds based on 3-carene isomerization products (major component of turpentine) without preliminary mixture separation.
Supporting agencies: The research was performed with financial support of BRFFR (project Х18МС-029).
About the Authors
A. Yu. Sidorenko
Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus
Belarus
Belarus
Sidorenko Alexander Yu. - Ph. D. (Chemistry), Head of the Laboratory, Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus.
36, Skorina Str., 220141, Minsk.
V. E. Agabekov
Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus
Belarus
Belarus
Agabekov Vladimir E. - Academician, D. Sc. (Chemistry), Professor, Director, Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus.
36, Skorina Str., 220141, Minsk.
K. P. Volcho
Novosibirsk Institute of Organic Chemistry of Siberian Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Volcho Konstantin P. - D. Sc. (Chemistry), Professor, Chief researcher, Novosibirsk Institute of Organic Chemistry Siberian Branch of the Russian Academy of Sciences.
9, Lavrentiev Ave., 630090, Novosibirsk.
N. F. Salakhutdinov
Novosibirsk Institute of Organic Chemistry of Siberian Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Salakhutdinov Nariman F. - Corresponding Member, D. Sc. (Chemistry), Professor, Head of the Department, Novosibirsk Institute of Organic Chemistry Siberian Branch of the Russian Academy of Sciences.
9, Lavrentiev Ave., 630090, Novosibirsk.
D. Yu. Murzin
Abo Akademi University
Finland
Finland
Murzin Dmitry Yu. - D. Sc. (Chemistry), Professor, Head of the Laboratory, Abo Akademi University.
Biskopsgatan 8, Turku-Abo, 20500.
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