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Specific features of n-decane vapors self-ignition in air at temperatures of 600–800 K

https://doi.org/10.29235/1561-8323-2020-64-6-747-756

Abstract

Experiments of n-decane/air self-ignition at the temperature range 600–800 K were carried out by rapid compression machine. It allowed obtaining temperature-concentration limits of transition from single-stage to two-stage ignition. High-speed video recording has let established that hot stage ignition always initiates near the piston surface or quartz window. These locations depend on gas temperature. Combustion of the test mixture occurs in the entire volume after that. Couple sequential photos of cool flame shows that it starts same near piston surface and has a complicated volumetric structure caused by the roll-up gas vortex. It is shown that partial n-decane pressure increasing during compression causes the non-equilibrium condensation process near the inner surfaces of combustion chamber. This leads to significant redistribution of n-decane concentration and determines local characteristics self-ignition of n-decane/air mixture.

About the Authors

V. V. Leschevich
A. V. Luikov Heat and Mass Transfer Institute of the National Academy of Sciences of Belarus
Belarus

Leschevich Vladimir V. – Ph. D. (Physics and Mathematics), Senior researcher

15, P. Brovka Str., 220072, Minsk



O. G. Penyazkov
A. V. Luikov Heat and Mass Transfer Institute of the National Academy of Sciences of Belarus
Belarus

Penyazkov Oleg G. – Academician, D. Sc. (Physics and Mathematics), Director

15, P. Brovka Str., 220072, Minsk



S. Yu. Shimchenko
A. V. Luikov Heat and Mass Transfer Institute of the National Academy of Sciences of Belarus
Belarus

Shimchenko Sergey Yu. – Researcher

15, P. Brovka Str., 220072, Minsk



References

1. Violi A., Yan S., Eddings E. G., Sarofim A. F., Granata S., Faravelli T., Ranzi E. Experimental formulation and kinetic model for JP-8 surrogate mixtures. Combustion Science and Technology, 2002, vol. 174, no. 11–12, pp. 399–417. https://doi.org/10.1080/00102200215080

2. Edwards T., Maurice L. Q. Surrogate Mixtures to Represent Complex Aviation and Rocket Fuels. Journal of Propulsion and Power, 2001, vol. 17, no. 2, pp. 461–466. https://doi.org/10.2514/2.5765

3. Pfahl U., Fieweger K., Adomeit G. Self-ignition of diesel-relevant hydrocarbon-air mixtures under engine conditions. Symposium (International) on Combustion, 1996, vol. 26, no. 1, pp. 781–789. https://doi.org/10.1016/s0082-0784(96)80287-6

4. Horning D. C. A study of the high-temperature auto-ignition and thermal decomposition of hydrocarbons. Report No. TSD-135. 2001. Available at: https://hanson.stanford.edu/dissertations/Horning_2001.pdf (accessed 24 September 2020).

5. Olchanski E., Burcat A. Decane oxidation in a shock tube. International Journal of Chemical Kinetics, 2006, vol. 38, no. 12, pp. 703–713. https://doi.org/10.1002/kin.20204

6. Zhukov V. P., Sechenov V. A., Starikovskii A. Yu. Autoignition of n-decane at high pressure. Combustion and Flame, 2008, vol. 153, no. 1–2, pp. 130–136. https://doi.org/10.1016/j.combustflame.2007.09.006

7. Shen H. P. S., Steinberg J., Vanderover J., Oehlschlaeger M. A. A shock tube study of the ignition of n-heptane, n-decane, n-dodecane, and n-tetradecane at elevated pressures. Energy & Fuels, 2009, vol. 23, no. 5, pp. 2482–2489. https://doi.org/10.1021/ef8011036

8. Dean A. J., Penyazkov O. G., Sevruk K. L., Varatharajan B. Autoignition of surrogate fuels at elevated temperatures and pressures. Proceedings of the Combustion Institute, 2007, vol. 31, no. 2, pp. 2481–2488. https://doi.org/10.1016/j.proci.2006.07.162

9. Nie X. F., Li P., Zhang C. H., Xie W., Li C. S., Li X. Y. Shock tube study of n-decane ignition at low pressures. Acta Mechanica Sinica, 2012, vol. 28, no. 1, pp. 79–82. https://doi.org/10.1007/s10409-011-0542-9

10. Titova N. S., Torokhov S. A., Starik A. M. On kinetic mechanisms of n-decane oxidation. Combustion, Explosion, and Shock Waves, 2011, vol. 47, no. 2, pp. 129–146. https://doi.org/10.1134/s0010508211020018

11. Strozzi C., Ossman H., Tsuzuki K., Sotton J., Bellenoue M. Autoignition of n-decane and multi-component surrogates of kerosene in an optical Rapid Compression Machine. Proceedings of 27th International Colloquium on the Dynamics of Explosions and Reactive Systems. Beijing, 2019, pp. 1–6.

12. Kumar K., Mittal G., Sung C. J. Autoignition of n-decane under elevated pressure and low-to-intermediate temperature conditions. Combustion and Flame, 2009, vol. 156, no. 6, pp. 1278–1288. https://doi.org/10.1016/j.combustflame.2009.01.009

13. Leschevich V. V., Martynenko V. V., Penyazkov O. G., Sevrouk K. L., Shabunya S. I. Auto-ignitions of a methane/air mixture at high and intermediate temperatures. Shock Waves, 2016, vol. 26, no. 5, pp. 657–672. https://doi.org/10.1007/s00193-016-0665-9

14. Leshchevich V. V., Penyazkov O. G., Shimchenko S. Yu. Ignition of Coal Microparticles in an Air Atmosphere and Their Influence on the Inflammation of Methane. Journal of Engineering Physics and Thermophysics, 2020, vol. 93, no. 4, pp. 1004–1014. https://doi.org/10.1007/s10891-020-02201-9

15. Leschevich V. V., Penyazkov O. G., Fomin N. A., Shimchenko S. Yu. Visualization and analysis of the burning particles motion in combustion chamber of a rapid compression machine. Journal of Flow Visualization and Image Processing, 2016, vol. 23, no. 1–2, pp. 1–14. https://doi.org/10.1615/jflowvisimageproc.2016019010

16. Gaydon A. G. The spectroscopy of flames. London, 1957. 279 p.

17. Doroshko M. V. High-temperature pyrolysis of propane and methane − the shock tube investigation. High Temperature Material Processes: An International Quarterly of High-Technology Plasma Processes, 2019, vol. 23, no. 2, pp. 165–179. https://doi.org/10.1615/hightempmatproc.2019030409


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ISSN 1561-8323 (Print)
ISSN 2524-2431 (Online)