SYNTHESIS AND STRUCTURE OF COMPLEXES OF COPPER(II) CHLORIDE AND BROMIDE WITH 4,5-DICHLOROISOTHIAZOLE-N-(2-HYDROXYETHYL)-3-CARBOXAMIDE
Abstract
Copper(II) chloride and bromide complexes with 4,5-dihlorizotiazol-N-(2-hydroxyethyl)-3-carboxamide (L) with the compositions [CuLHal2 ]n , where Hal = Cl– , Br– , are synthesized. The X-ray analysis revealed that the ligand is coordinated to the copper(II) atoms tridentate by the nitrogen atom of the heterocycle and two exocyclic oxygen atoms to form polymer chains. The copper bromide complex showed a synergistic effect in the compositions of insecticides Kerber and Vitan.
About the Authors
V. I. Potkin
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
A. V. Kletskov
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
E. V. Lider
Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk
Russian Federation
Russian Federation
L. G. Lavrenova
Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk
Russian Federation
Russian Federation
R. M. Zolotar
Institute of Bioorganic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
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