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Sorption of acetic acid vapors from the air by fibrous anion exchangers with ternary and quaternary amino groups

https://doi.org/10.29235/1561-8323-2019-63-5-548-553

Abstract

A fibrous anion exchanger with ternary amino groups of dimethylaminopropylamine was obtained on the base of a polyacrylonitrile fiber by the previously proposed method of catalytic amination of nitrile groups. A fibrous anion exchanger with strong base functional groups was synthesized on the base of this material by the reaction of alkylation of its groups with epichlorohydrin solutions. Their exchange capacities, acid-base properties, sorption of acetic acid vapors from air with different relative humidity were determined. The boundary and optimal conditions of application of the obtained ion exchangers in the processes of air purification from acetic acid and the dynamic characteristics of filtration layers were established.

About the Authors

Evgenii G. Kosandrovich
Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus
Belarus

Kasandrovich Evgenii Genrikhovich - Ph. D. (Chemistry), Associate professor, Head of the Laboratory.

13, Surganov Str., 220072, Minsk



Larisa N. Shachenkova
Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus
Belarus

Shachenkova Larisa Nikolaevna - Ph. D. (Chemistry), Senior researcher.

13, Surganov Str., 220072, Minsk



Vladimir S. Soldatov
Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus
Belarus

Soldatov Vladimir Sergeevich - Academician, D. Sc. (Chemistry), Professor, Chief researcher.

13, Surganov Str., 220072, Minsk



References

1. Soldatov V. S. Syntheses and the main properties of FIBAN fibrous ion exchangers. Solvent extraction and ion exchange, 2008, vol. 26, no. 5, pp. 457-513. https://doi.org/10.1080/07366290802301358

2. Zverev M. P. Fibre chemisorbents - material for environmental protection. A review. Fibre Chemistry, 2002, vol. 34, no. 6, pp. 456-465. https://doi.org/10.1023/a:1022972511231

3. Druzhinina T. V., Nazar’ina L. A. Chemisorption fibres based on graft copolymers: fabrication and properties. A review. Fibre Chemistry, 1999, vol. 31, no. 4, pp. 252-262. https://doi.org/10.1007/bf02358329

4. Egiazarov Yu. G., Potapova L. L., Radkevich V. Z., Soldatov V. S., Shunkevich A. A., Cherches B. Kh. New catalytic systems based on fibrous ion exchangers. Khimiya v interesakh ustoychivogo razvitiya = Chemistry for Sustainable Development, 2001, no. 9, pp. 417-431 (in Russian).

5. Soldatov V. S., Kosandrovich E. G. Ion exchangers for air purification. Ion Exchange and Solvent Extraction Series, 2011, vol. 20, pp. 45-117. https://doi.org/10.1201/b10813-3

6. Schlegelmilch M., Streese J., Stegmann R. Odour management and treatment technologies: An overview. Waste Management, 2005, vol. 25, no. 9, pp. 928-939. https://doi.org/10.1016/j.wasman.2005.07.006

7. Gostelow P., Parsons S. A., Stuetz R. M. Odour measurements for sewage treatment works. Water Research, 2001, vol. 35, no. 3, pp. 579-597. https://doi.org/10.1016/s0043-1354(00)00313-4

8. Soldatov V. S. Potentiometric titration of ion exchangers. Reactive and Functional Polymers, 1998, vol. 38, no. 2-3, pp. 73-112. https://doi.org/10.1016/s1381-5148(98)00018-2

9. Nesteronok P. V., Soldatov V. S. A method for determination of polyampholytes’ acidity parameters. Vestsi Nat-syyanal’nai akademii navuk Belarusi. Seryya khimichnykh navuk = Proceedings of the National Academy of Sciences of Belarus. Chemistry Series, 2013, no. 2, pp. 31-36 (in Russian).

10. Kosandrovich E. G., Soldatov V. S. Ammonia sorption from air by FIBAN K-1 fibrous sulphonic cation exchanger. Vestsi Natsyyanal’nai akademii navuk Belarusi. Seryya khimichnykh navuk = Proceedings of the National Academy of Sciences of Belarus. Chemistry Series, 2004, no. 3, pp. 95-98 (in Russian).

11. Peregud E. A. Chemical air analysis. Moscow, 1976. 328 p. (in Russian).

12. Korshunova T. A., Kosandrovich E. G., Soldatov V. S. Hydrogen chloride absorption from the air with the fibrous ion exchangers fiban. Russian Journal of Applied Chemistry, 2010, vol. 83, no. 7, pp. 1159-1169. https://doi.org/10.1134/s1070427210070013

13. Subbotin A. I., Tkachenko V. I. Air purification from acetic acid vapors with ion exchangers. Plasticheskiye massy = Plastics, 1975, no. 5, pp. 38-39 (in Russian).

14. Kasatkin A. G. Basic processes and apparatuses of chemical technology. Moscow, 1973. 752 p. (in Russian).


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ISSN 1561-8323 (Print)
ISSN 2524-2431 (Online)