MATHEMATICS
PHYSICS
The quasi-Newtonian model of the reci ci procal invariant Hamil il tonian dynamics of gravitating masses, which obeys the Gibson maximum tension principle, is proposed. The symmetry of the model is defined by the Lorentz complex group with real metric. The mass of a model object is the only ly free parameter that defines space-time momentum-energy scales as well ll as frequency characteristics of the model. In the case of small masses there appears the classical analog of the Schrödinger "bouncing" (Zitterbewegung). In the limiting case of the Universe mass the model reproduces the "cyclic" variant of traditional cosmology. The availability of Gibbon’s limit results both in a universal relationship between energy density and cosmological expansion rate, as well as in the existence of the upper and lower limits of these quantities.
CHEMISTRY
Polythermic dependences of the phase transformation degree during Sr2FeMoO6–d crystallization by the solid phase method have been studied for powders synthesized from the stoichiometric mixture of the oxides SrCO3 Fe2O3, MoO3 and from the partially reduced precursors SrFeO3–x and SrMoO4–y. It is found that the general rule for all samples is a transition from the kinetic mode of interaction to the diffusion one. In this case, the reaction product layer is formed and is increased with its blocking action. However, it should be mentioned that for the samples synthesized from a mixture of simple oxides, the kinetic stage of solid-phase interactions is mixed with the presence of some fraction of the diffusion part due to the formation of intermediate reaction products. When α is increased, the fraction of the diffusion part grows. The use of the partially reduced precursors SrFeO3–x and SrMoO4–y with submicron grains allows one to synthesize the single-phase compound Sr2FeMoO6–d with the superstructure ordering of Fe3+/Mo+5 cations. In this case, the kinetic difficulties of the Sr2FeMoO6–d phase formation are significantly reduced by increase in the diffusion mobility of Fe3+ and Mo+5 cations and by decrease in the distance of their motion to the reaction zone.
The transformation of the intermolecular complex of chromium (III)–polymer into the intramolecular one was revealed to be the main reason for degradation of polyelectrolyte hydrogels based on sulfonated and carboxylated polyacrylamides crosslinked by chromium (III) acetate during thermal aging, while the mineralized water addition caused polymer salts to precipitate. Hydrogel destruction occurred at a relatively high content of carboxylate groups formed due to the hydrolysis of amide or substituted amide groups. NMR 13C and NMR 1H spectroscopy showed that the hydrolysis of the functional groups in polyelectrolyte hydrogel containing a sulfo group proceeded slowly, thus resulting in a higher resistance to thermal aging as compared to that based on carboxylated polyacrylamide.
BIOLOGY
MEDICINE
EARTH SCIENCES
TECHNICAL SCIENCES
SOCIAL SCIENCES AND HUMANITIES
AGRARIAN SCIENCES
The results of studying the influence of some factors on the efficiency of the cattle pick-up are presented in the article. It is established that the level of recoverability of the oocyte-cumulus complexes from the number of punctured follicles is 68.7%. The yield of oocytes per one aspiration is 2.7, including per one positive aspiration for extraction – 3.3. Most acceptable for aspiration is the 17G dia needle regardless of the vacuum level. The greatest number of aspirated follicles (6.2 and 8.0) and picked-up oocytes (4.0 to 5.5) is observed when for simulation the follicle-stimulating Pluset hormone is used at a dose of 750 I. E. with or without the use of the progestagen drug Crestar during the stimulation process.
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