MATHEMATICS
PHYSICS
It is shown that lenses based on the metal – dielectric (MD) structure are energetically more efficient in ultraviolet and violet ranges of wavelengths. Phase characteristics of flat lenses in ultraviolet as well as in visible ranges for the p-polarized light have a concave shape, which is the necessary condition of focusing. For the first time, direct measurement is made of the flat optically thin two-layered MD-structure (Ag/SiO2 ). It has been found experimentally that for an incident spherical wave with radial polarization (p-polarization), the focusing regime is realized, and with azimuthal polarization (s-polarization) the channeling regime is realized.
The crystal structure and magnetic properties of Bi1–x Cax Fe1–x Mnx O3 (x ≤ 0.22) have been studied. It was shown that the rhombohedral (R3c) polar phase at x > 0.18 transforms into the nonpolar orthorhombic phase (Pnma). The polar phase is antiferromagnetic and metamagnetic at x < 0.1. The polar and nonpolar phases are weak ferromagnets with remnant magnetization around 0.07 emu/g (x = 0.18 and х = 0.22). Decreasing the temperature leads to the state close to antiferromagnetic.
CHEMISTRY
Tea extracts (TE) and permeate of culture liquid (PCL) of Penicillium adametzii LF F-2044.1 were used in forming of iron-containing nanocomposite PVP-Fe-PEI including polyvinylpyrrolidone (PVP; 24 kDa) and polyethyleneimine (PEI; 1800 Da). Either TE or PCL were added to the reaction mixture or PVP-Fe-PEI was introduced into TE or PCL. PVP-Fe-PEI composite is formed with TE. PCL was associated with Fe3+ butdon’t reduce its. Zero-valent iron can be produced in decreasing PCL concentration and increasing NaBH4 concentration. PVP-Fe-PEI composite was conjugated to periodate-oxidized dextran T20.
Copper(II) chloride and bromide complexes with 4,5-dihlorizotiazol-N-(2-hydroxyethyl)-3-carboxamide (L) with the compositions [CuLHal2 ]n , where Hal = Cl– , Br– , are synthesized. The X-ray analysis revealed that the ligand is coordinated to the copper(II) atoms tridentate by the nitrogen atom of the heterocycle and two exocyclic oxygen atoms to form polymer chains. The copper bromide complex showed a synergistic effect in the compositions of insecticides Kerber and Vitan.
A conjugate has been obtained in the reaction of chloramphenicol 3-hemisuccinate with diethylenetriaminepentaacetic acid N1 -(2-aminoethylamide) Eu3+-complexonate. Kinetic and equilibrium parameters of conjugate binding to polyclonal antichloramphenicol antibodies biospecifically immobilized onto microtiter plate wells were determined. It was concluded that the new bioconjugate can be used in a lanthanide immunofluorometric assay of chloramphenicol.
BIOLOGY
TECHNICAL SCIENCES
SOCIAL SCIENCES AND HUMANITIES
AGRARIAN SCIENCES
The changes of biochemical indices of mineralization and humification of organic substances in high-fertility derno-podzolic sandy-loam soil depending on the application of different fertilizer systems were established using the data on the activity of cellulolytic and amylolytic microbial communities, as well as the results of enzymatic soil diagnostics (hydrolytic and oxidative enzymes). The application of N90+30P15K30 was shown to provide high and sustainable crop yields under a moderate level of organic substances mineralization in С and N-circles.
ISSN 2524-2431 (Online)