MATHEMATICS
The article deals with linear operators A with a spectral radius equal 1 in Hilbert and Banach spaces, for which the successive approximations xn+1= Axn + f with an arbitrarily initial approximation x0 converge to one of the solutions of the equation x = Ax + f (under the condition that these solutions exist).
The paper deals with extremal properties of diagonal Hermite-Pad’e approximants of type I for exponential system {eλpz}kp=0with arbitrary λ0, λ1, …, λk. Proved theorems complement known results of P. P. Borwein, F. Wielonsky.
PHYSICS
CHEMISTRY
The novel stabilizing ligand, 5-mercaptotetrazole-1-acetic acid, has been applied for a simple synthesis of noble metal nanoparticles in the aqueous medium. This method is based on the reduction of metal salts in water in the presence of available 5-mercaptotetrazole-1-acetic acid. The interaction of the nanoparticle surface with the ligand has been investigated. According to quantum chemical calculations, the most stable structure has been realized when the capping ligand binds with the surface of nanoparticles through both sulphur and nitrogen N4 atoms. Free carboxyl groups provide good redissolvation in water.
Obtained particles are attractive as precursors for catalysts, as well as biologically active systems with antibacterial and fungicidal properties.
The research of hydrocarbonic substitutes at quaternary ammonium salt nitrogen atom length influence and the kind of plasticizer on tetraftoroborate electrodes analytical characteristics has been carried out. The functions of electrodes have theoretical gradients. The detection limits change from 5.0 · 10–6 to 1.3 · 10–6 mol/l. It is shown that the reason of potentiometric selectivity coefficient decrease is the increase of the steric difficulty of the QAS exchange center.
Herein, the environmentally friendly synthesis of the earlier unknown phospholipid analog of kinetin riboside was carried out using phospholipase D of Streptomyces netropsis. Kinetin riboside and soybean lecithin served as substrates. A maximum degree of nucleoside conversion to 5′-phosphatidyl derivative of kinetin riboside at 37°С to 6 h exceeds 95%. The structure of target product was confirmed by UV and 1Н NMR spectroscopy.
P
olysulfone hollow fiber ultrafiltration membranes cast from the polysulfone solution in dimethylacetamide containing PEG 400 as porophore and hydrophilized with additives of polyvinylpyrrolidon K-90 have been tested after long term storage. The specific influence of the dilute solutions of PEG with M = 6000–20000 on the membrane permeability has been found. The short term treatment by PEG dilute solutions has restored the pore structure and the membrane permeability following the capillary contraction. It is assumed that the detected effect is caused by the wedge action of PEG due to its interaction with polyvinylpyrrolidone in the membrane matrix.
Aseries of purine modified nucleosides with 2′,3′-difluoro-β-D-arabinofuranosyl moiety have been synthesized starting from derivative of 2′,3′-dideoxy-2′,3′-difluoro-D-arabinofuranose via anionic glycosylation reaction of salts of purine heterocyclic bases by α-bromide as the universal sugar precursor.2,6-Disubstituted purine 2′,3′-difluoro-D-arabinofuranosyl nucleosides and guanine nucleoside analogue were prepared by chemical transformations of protected arabinosides of 2,6-dichloropurine or 2-amino-6-chloropurine as key intermediates for constructing diverse nucleoside analogues of this class.
BIOLOGY
The methods for identifying M-virus resistance genes of potato were developed.Gene Gm of extreme PVM resistance is rare and available for the present only in breeding material.On the contrary, hypersensitivity gene Rm is quite widely represented in Belarusian and foreign potato cultivars providing their resistance to this pathogen.Potato cultivars and hybrids, selected for the availability of markers GP250510, GP283320, UBC8221079 to gene Rm and marker SC878885 to gene Gm, are the valuable donors of resistance to this virus and are recommended for use in breeding.
EARTH SCIENCES
A traditional hydrocarbon raw material includes oil deposits explored in 80 oil fields in the territory of Belarus. The paths of undiscovered reserves utilization are presented on the basis of the analysis of the resource hydrocarbon potential taking into account its exploration up to 53%. Promising objects are validated with minimal oil reserves to introduce them into prospect drilling with an assurance of their development efficiency.
TECHNICAL SCIENCES
SOCIAL SCIENCES AND HUMANITIES
ISSN 2524-2431 (Online)